Problems in Structural Inorganic Chemistry

Author: Wai-Kee Li,Hung Kay Lee,Dennis Kee Pui Ng,Kendrew Kin Wah Mak,Yu-San Cheung,Thomas Chung Wai Mak

Publisher: Oxford University Press, USA

ISBN: 0198823908

Category: Science

Page: 480

View: 5852

This book consists of over 422 problems and their acceptable answers on structural inorganic chemistry at the senior undergraduate and beginning graduate level. The central theme running through these questions is symmetry, bonding and structure: molecular or crystalline. A wide variety of topics are covered, including Electronic States and Configurations of Atoms and Molecules, Introductory Quantum Chemistry, Atomic Orbitals, Hybrid Orbitals, Molecular Symmetry, Molecular Geometry and Bonding, Crystal Field Theory, Molecular Orbital Theory, Vibrational Spectroscopy, Crystal Structure, Transition Metal Chemistry, Metal Clusters: Bonding and Reactivity, and Bioinorganic Chemistry. The questions collected here originate from the examination papers and take-home assignments arising from the teaching of courses in Chemical Bonding, Elementary Quantum Chemistry, Advanced Inorganic Chemistry, and X-Ray Crystallography by the book's two senior authors over the past five decades. The questions have been tested by generations of students taking these courses. The questions in this volume cover essentially all the topics in a typical course in structural inorganic chemistry. The text may be used as a supplement for a variety of inorganic chemistry courses at the senior undergraduate level. It also serves as a problem text to accompany the book Advanced Structural Inorganic Chemistry, co-authored by W.-K. Li, G.-D. Zhou, and T. C. W. Mak (Oxford University Press, 2008).

Anorganische Strukturchemie

Author: Ulrich Müller

Publisher: Springer-Verlag

ISBN: 9783834895455

Category: Science

Page: 394

View: 5493

In dem Lehrbuch für Studenten der Chemie werden wichtige Aspekte und Zusammenhänge der Strukturen anorganisch-chemischer Verbindungen dargelegt. Die Strukturmerkmale von Molekülverbindungen wie auch von Festkörpern werden behandelt und an anschaulichen Beispielen erläutert. So weit wie möglich werden diese Strukturen mit einfachen und eingängigen Theorien erklärt (Gillespie-Nyholm-Theorie, Ligandenfeldtheorie, Ionenradienverhältnisse, Pauling-Regeln, (8-N)-Regel u.ä.), es wird aber auch auf die moderne Bindungstheorie eingegangen. Wichtige Festkörperstrukturen werden wiederholte Male und dabei jedes Mal von einem anderen Standpunkt betrachtet. Zusammenhänge zwischen Struktur und physikalischen Eigenschaften werden herausgearbeitet.

Structural Methods in Molecular Inorganic Chemistry

Author: D. W. H. Rankin,Norbert Mitzel,Carole Morrison

Publisher: John Wiley & Sons

ISBN: 1118462882

Category: Science

Page: 496

View: 9751

Determining the structure of molecules is a fundamental skillthat all chemists must learn. Structural Methods in MolecularInorganic Chemistry is designed to help readers interpretexperimental data, understand the material published in modernjournals of inorganic chemistry, and make decisions about whattechniques will be the most useful in solving particular structuralproblems. Following a general introduction to the tools and concepts instructural chemistry, the following topics are covered indetail: • computational chemistry • nuclear magnetic resonance spectroscopy • electron paramagnetic resonance spectroscopy • Mössbauer spectroscopy • rotational spectra and rotational structure • vibrational spectroscopy • electronic characterization techniques • diffraction methods • mass spectrometry The final chapter presents a series of case histories,illustrating how chemists have applied a broad range of structuraltechniques to interpret and understand chemical systems. Throughout the textbook a strong connection is made betweentheoretical topics and the real world of practicing chemists. Eachchapter concludes with problems and discussion questions, and asupporting website contains additional advanced material. Structural Methods in Molecular Inorganic Chemistry is anextensive update and sequel to the successful textbookStructural Methods in Inorganic Chemistry by Ebsworth,Rankin and Cradock. It is essential reading for all advancedstudents of chemistry, and a handy reference source for theprofessional chemist.

Advanced Structural Inorganic Chemistry

Author: Wai-Kee Li,Gong-Du Zhou,Thomas C. W. Mak

Publisher: Oxford University Press

ISBN: 0199216940

Category: Science

Page: 819

View: 911

A revised and updated English edition of a textbook based on teaching at the final year undergraduate and graduate level. It presents structure and bonding, generalizations of structural trends, crystallographic data, as well as highlights from the recent literature.

Spectroscopy in Inorganic Chemistry

Author: C.N.R. Rao

Publisher: Elsevier

ISBN: 032315090X

Category: Science

Page: 424

View: 4242

Spectroscopy in Inorganic Chemistry, Volume I describes the innovations in various spectroscopic methods that are particularly effective in inorganic chemistry studies. This volume contains nine chapters; each chapter discusses a specific spectroscopic method, their fundamental principles, methods, instrumentation, advantages disadvantages, and application. Chapter 1 covers some of the general principles and experiments that have been used in the recording and interpretation of crystal spectra of molecules that contain transition-metal ions. Chapter 2 illustrates the application of spectroscopic techniques to the photochemistry of small inorganic molecules, non-transition-metal compounds, and transition-metal complexes. The remaining chapters examine several spectroscopic methods, such as matrix isolation, mass, soft X-ray, and Mössbauer spectroscopies, high-resolution NMR, and nuclear quadrupole resonance, with a particular emphasis on their effective application in inorganic chemistry studies. This book will be of great benefit to inorganic chemists, spectroscopists, and inorganic chemistry teachers and students.

Concepts And Problems In Inorganic Chemistry

Author: P. S. Raghavan

Publisher: Discovery Publishing House

ISBN: 9788171414185

Category:

Page: 425

View: 4579

Contents: Periodic Table and Periodic Properties, Elements of Row 2 of the Periodic Table, Hydrogen and Hydrides, Group I: The Alkali Metals, Group II: The Alkaline Earths, The p-Block Elements, Group III: The Boron Group, Group IV: The Carbon Group, Group V: The Nitrogen Group, Group VI: The Oxygen Group, Group VIII: The Halogens, The Noble Gases, Metals and Metallurgy, Transition Metals, Coordination Compounds, More Solved Problems.

Structural Inorganic Chemistry

Author: Alexander Frank Wells

Publisher: Oxford University Press

ISBN: 0199657637

Category: Science

Page: 1416

View: 6228

The fifth edition of this widely acclaimed work has been reissued as part of the Oxford Classic Texts series. The book includes a clear exposition of general topics concerning the structures of solids, and a systematic description of the structural chemistry of elements and their compounds. The book is divided into two parts. Part I deals with a number of general topics, including the properties of polyhedra, the nature and symmetry of repeating patterns, and the ways in which spheres, of the same or different sizes, can be packed together. In Part II the structural chemistry of the elements is described systematically, arranged according to the groups of the Periodic Table.

Inorganic Chemistry in Focus III

Author: Gerd Meyer,Dieter Naumann,Lars Wesemann

Publisher: John Wiley & Sons

ISBN: 3527609091

Category: Science

Page: 375

View: 4835

Metal clusters are on the brink between molecules and nanoparticles in size. With molecular, nano-scale, metallic as well as non-metallic aspects, metal clusters are a growing, interdisciplinary field with numerous potential applications in chemistry, catalysis, materials and nanotechnology. This third volume in the series of hot topics from inorganic chemistry covers all recent developments in the field of metal clusters, with some 20 contributions providing an in-depth view. The result is a unique perspective, illustrating all facets of this interdisciplinary area: * Inter-electron Repulsion and Irregularities in the Chemistry of Transition Series * Stereochemical Activity of Lone Pairs in Heavier Main Group Element Compounds * How Close to Close Packing? * Forty-Five Years of Praseodymium Diiodide * Centered Zirconium Clusters * Titanium Niobium Oxychlorides * Trinuclear Molybdenum and Tungsten Cluster Chalcogenides * Current State of (B,C,N)-Compounds of Calcium and Lanthanum * Ternary Phases of Lithium with Main-Group and Late-Transition Metals * Polar Intermetallics and Zintl Phases along the Zintl Border * Rare Earth Zintl Phases * Structure-Property Relationships in Intermetallics * Ternary and Quaternary Niobium Arsenide Zintl Phases * The Building Block Approach to Understanding Main-Group-Metal Complex Structures * Cation-Deficient Quaternary Thiospinels * A New Class of Hybrid Materials via Salt Inclusion Synthesis * Layered Perrhenate and Vanadate Hybrid Solids * Hydrogen Bonding in Metal Halides * Syntheses and Catalytic Properties of Titanium Nitride Nanoparticles * Solventless Thermolysis * New Potential Scintillation Materials in Borophosphate Systems. With its didactical emphasis, this volume addresses a wide readership, such that both students and specialists will profit from the expert contributions.

Computer Modeling in Inorganic Crystallography

Author: C.Richard A. Catlow

Publisher: Elsevier

ISBN: 9780080502458

Category: Science

Page: 340

View: 5528

Computer simulation techniques are now having a major impact on almost all areas of the physical and biological sciences. This book concentrates on the application of these methods to inorganic materials, including topical and industrially relevant systems including zeolites and high Tc superconductors. The central theme of the book is the use of modern simulation techniques as a structural tool in solid state science. Computer Modelling in Inorganic Crystallography describes the current range of techniques used in modeling crystal structures, and strong emphasis is given to the use of modeling in predicting new crystal structures and refining partially known structures. It also reviews new opportunities being opened up by electronic structure calculation and explains the ways in which these techniques are illuminating our knowledge of bonding in solids. Includes a thorough review of the technical basis of relevant contemporary methodologies including minimization, Monte-Carlo, molecular dynamics, simulated annealing methods, and electronic structure methods Highlights applications to amorphous and crystalline solids Surveys simulations of surface and defect properties of solids Discusses applications to molecular and inorganic solids

Inorganic Chemistry

Author: Catherine E. Housecroft,A. G. Sharpe

Publisher: Pearson Education

ISBN: 9780130399137

Category: Science

Page: 949

View: 3368

Inorganic Chemistry "Catherine E. Housecroft and Alan G. Sharpe" This book has established itself as a leading textbook in the subject by offering a fresh and exciting approach to the teaching of modern inorganic chemistry. It gives a clear introduction to key principles with strong coverage of descriptive chemistry of the elements. Special selected topics chapters are included, covering inorganic kinetics and mechanism, catalysis, solid state chemistry and bioinorganic chemistry. A new full-colour text design and three-dimensional illustrations bring inorganic chemistry to life. Topic boxes have been used extensively throughout the book to relate the chemistry described in the text to everyday life, the chemical industry, environmental issues and legislation, and natural resources. Teaching aids throughout the text have been carefully designed to help students learn effectively. The many worked examples take students through each calculation or exercise step by step, and are followed by related self-study exercises tackling similar problems with answers to help develop their confidence. In addition, end-of-chapter problems reinforce learning and develop subject knowledge and skills. Definitions boxes and end-of-chapter checklists provide excellent revision aids, while further reading suggestions, from topical articles to recent literature papers, will encourage students to explore topics in more depth. New to this edition Many more self-study exercises have been introduced throughout the book with the aim of making stronger connections between descriptive chemistry and underlying principles. Additional 'overview problems' have been addedto the end-of-chapter problem sets. The descriptive chemistry has been updated, with many new results from the literature being included. Chapter 4 Bonding in polyatomic molecules, has been rewritten with greater emphasis on the use of group theory for the derivation of ligand group orbitals and orbital symmetry labels. There is more coverage of supercritical fluids and 'green' chemistry. The new full-colour text design enhances the presentation of the many molecular structures and 3-D images. Supporting this edition Companion website featuring multiple-choice questions and rotatable 3-D molecular structures, available at "www.rearsoned.co.uk/housecroft," For full information, including details of lecturer material, see the Contents list inside the book. ASolutions Manual, written by Catherine E. Housecroft, with detailed solutions to all end-of-chapter problems within the text is available for purchase separately ISBN 0131 39926 8. "Catherine E. Housecroft" is Professor of Chemistry at the University of Basel, Switzerland. She is the author of a number of textbooks and has extensive teaching experience in the UK, Switzerland, South Africa and the USA. "Alan G. Sharpe" is a Fellow of Jesus College, University of Cambridge, UK and has had many years of experience teaching inorganic chemistry to undergraduates

Inorganic Biochemistry

An Introduction

Author: J. A. Cowan

Publisher: John Wiley & Sons

ISBN: 9780471188957

Category: Science

Page: 440

View: 9912

Developments in the expanding field of inorganic biochemistry have led to major additions to this teaching text. The author illustrates the use of basic principles to tackle important problems in the field of inorganic biochemistry.

Unusual Structures and Physical Properties in Organometallic Chemistry

Author: Marcel Gielen,Rudolph Willem,Bernd Wrackmeyer

Publisher: John Wiley & Sons

ISBN: 0470855614

Category: Science

Page: 446

View: 2287

The principal idea of this volume is to offer a Capita Selecta of unconventional and thought-provoking topics in organometallic chemistry, presented by experts in each field. As intended, this approach leads either to reviews covering a specific uncommon class of organometallic compounds or to overviews which relate uncommon physical properties with various classes of organometallic compounds. The contributions are streamlined thus onto two main axes - unusual properties reflecting structures and bonding situations, on the one hand, and uncommon structural features or structure-reactivity relationships, on the other. Extensive cross-referencing of useful information is provided, making this volume accessible for people working in rather different areas of organometallic chemistry. The synthesis of molecules with 'extreme' properties is a challenge for all those working in organometallic chemistry, irrelevant of theoretical/computational, synthetic or application interests. This book presents case studies at the interface of these overlapping interests. Unusual Structures and Physical Properties in Organometallic Chemistry: * Provides test cases for computational and theoretical models * Presents a challenge for synthetic chemists * Provides ideal show cases for analytical techniques This volume will be an invaluable reference for researchers in organometallic chemistry, computational and theoretical chemistry, NMR and other spectroscopic methods.

Challenges in Molecular Structure Determination

Author: Manfred Reichenbächer,Jürgen Popp

Publisher: Springer Science & Business Media

ISBN: 3642243894

Category: Science

Page: 482

View: 8700

Taking a problem-based approach, the authors provide a practice-oriented and systematic introduction to both organic and inorganic structure determination by spectroscopic methods. This includes mass spectrometry, vibrational spectroscopies, UV/VIS spectroscopy and NMR as well as applying combinations of these methods. The authors show how to elucidate chemical structures with a minimal number of spectroscopic techniques. Readers can train their skills by more than 400 problems with varying degree of sophistication. Interactive Powerpoint-Charts are available as Extra Materials to support self-study.

Progress in Inorganic Chemistry

Author: Stephen J. Lippard

Publisher: John Wiley & Sons

ISBN: 0470166886

Category: Science

Page: 714

View: 8717

This comprehensive series of volumes on inorganic chemistry provides inorganic chemists with a forum for critical, authoritative evaluations of advances in every area of the discipline. Every volume reports recent progress with a significant, up-to-date selection of papers by internationally recognized researchers, complemented by detailed discussions and complete documentation. Each volume features a complete subject index and the series includes a cumulative index as well.

Symmetry and Group theory in Chemistry

Author: M Ladd

Publisher: Elsevier

ISBN: 0857099779

Category: Science

Page: 432

View: 8084

A comprehensive discussion of group theory in the context of molecular and crystal symmetry, this book covers both point-group and space-group symmetries. Provides a comprehensive discussion of group theory in the context of molecular and crystal symmetry Covers both point-group and space-group symmetries Includes tutorial solutions

Chirality in Transition Metal Chemistry

Molecules, Supramolecular Assemblies and Materials

Author: Hani Amouri,Michel Gruselle

Publisher: John Wiley & Sons

ISBN: 047072160X

Category: Science

Page: 260

View: 7122

Chirality in Transition Metal Chemistry is an essential introduction to this increasingly important field for students and researchers in inorganic chemistry. Emphasising applications and real-world examples, the book begins with an overview of chirality, with a discussion of absolute configurations and system descriptors, physical properties of enantiomers, and principles of resolution and preparation of enantiomers. The subsequent chapters deal with the the specifics of chirality as it applies to transition metals. Some reviews of Chirality in Transition Metal Chemistry "...useful to students taking an advanced undergraduate course and particularly to postgraduates and academics undertaking research in the areas of chiral inorganic supramolecular complexes and materials." Chemistry World, August 2009 “...the book offers an extremely exciting new addition to the study of inorganic chemistry, and should be compulsory reading for students entering their final year of undergraduate studies or starting a Ph.D. in structural inorganic chemistry.” Applied Organometallic Chemistry Volume 23, Issue 5, May 2009 “...In conclusion the book gives a wonderful overview of the topic. It is helpful for anyone entering the field through systematic and detailed introduction of basic information. It was time to publish a new and topical text book covering the important aspect of coordination chemistry. It builds bridges between Inorganic, organic and supramolecular chemistry. I can recommend the book to everybody who is interested in the chemistry of chiral coordination compounds .” Angew. chem. Volume 48, Issue 18, April 2009 About the Series Chirality in Transition Metal Chemistry is the latest addition to the Wiley Inorganic Chemistry Advanced Textbook series. This series reflects the pivotal role of modern inorganic and physical chemistry in a whole range of emerging areas such as materials chemistry, green chemistry and bioinorganic chemistry, as well as providing a solid grounding in established areas such as solid state chemistry, coordination chemistry, main group chemistry and physical inorganic chemistry.